Investigating the freezing of colloids by X-rays radiography and tomography: recent results, limitations and potential for further progress
Abstract
Understanding the critical parameters controlling the stability of solidification interfaces in colloidal systems is a necessary step in many domains were the freezing of colloids is present, such as materials science or geophysics. What we understand so far of the solidification of colloidal suspensions is derived primarily from the analogies with dilute alloys systems, or the investigated behaviour of single particles in front of a moving interface and is still a subject of intense work. A more realistic, multi-particles model should account for the particles movement, the various possible interactions between the particles and the multiple interactions between the particles and the solid/liquid cellular interface. In order to bring new experimental observations, we choose to investigate the stability of a cellular interface during directional solidification of colloidal suspensions by using X-ray radiography and tomography. I will present recent experimental results of ice growth (ice lenses) and particle redistribution observations, their implications, and open the discussion regarding the limitations of the technique and the potential for further progress in the field using this approach.