Finite element methods for multicomponent convection-diffusion

Mass transfer in multicomponent systems occurs through convection and diffusion. For a viscous Newtonian flow, convection may be modelled using the Navier–Stokes equations, whereas the diffusion of multiple species within a common phase may be described by the generalised Onsager–Stefan–Maxwell equations. In this talk we present a novel finite element formulation which fully couples convection and diffusion with these equations. In the regime of vanishing Reynolds number, we use the principles of linear irreversible dynamics to formulate a saddle point system which leads to a stable formulation and a convergent discretisation. The wide scope of applications for this novel numerical method is illustrated by considering transport of oxygen through the lungs, gas separation processes, mixing of water and methanol and salt transport in electrolytes.