Inverse Problems in Electrochemistry

A simple experiment in the field of electrochemistry involves  controlling the applied potential in an electrochemical cell. This  causes electron transfer to take place at the electrode surface and in turn this causes a current to flow. The current depends on parameters in  the system and the inverse problem requires us to estimate these  parameters given an experimental trace of the current. We briefly  describe recent work in this area from simple least squares approximation of the parameters, through bootstrapping to estimate the distributions of the parameters, to MCMC methods which allow us to see correlations between parameters.