Many soft materials, such as elastomers and hydrogels, are made of long chain molecules crosslinked to form a three-dimensional network. Their mechanical properties depend on network parameters such as chain density, chain length distribution and the functionality of the crosslinks. Understanding the relationships between the topology of polymer networks and their mechanical properties has been a long-standing challenge in polymer physics.

In this work, we focus on so-called “near-ideal” networks, which are produced by the cross-coupling of star-like macromolecules with well-defined chain length. We developed a computational approach based on random discrete networks, according to which the polymer network is represented by an assembly of non-linear springs connected at junction points representing crosslinks. The positions of the crosslink points are determined from the conditions of mechanical equilibrium. Scaling relations for the elastic modulus and maximum extensibility of the network were obtained. Our scaling relations contradict some predictions of classical estimates of rubber elasticity and have implications for the interpretation of experimental data for near-ideal polymer networks.

Reference: G. Alame, L. Brassart. Relative contributions of chain density and topology to the elasticity of two-dimensional polymer networks. Soft Matter 15, 5703 (2019).

We aim to generate gene coexpression networks from gene expression data. In our networks, nodes represent genes and edges depict high positive correlation in their expression across different samples. Methods based on Pearson correlation are the most commonly used to generate gene coexpression networks. We propose the use of distance correlation as an effective alternative to Pearson correlation when constructing gene expression networks. Our methodology pipeline includes a thresholding step which allows us to discriminate which pairs of genes are coexpressed. We select the value of the threshold parameter by studying the stability of the generated network, rather than relying on exogenous biological information known a priori.

Identifying systemically important countries is crucial for global financial stability. In this work we use (multilayer) network methods to identify systemically important countries. We study the financial system as a multilayer network, where each layer represent a different type of financial investment between countries. To rank countries by their systemic importance, we implement MultiRank, as well a simplistic model of financial contagion. In this first model, we consider that each country has a capital buffer, given by the capital to assets ratio. After the default of an initial country, we model financial contagion with a simple rule: a solvent country defaults when the amount of assets lost, due to the default of other countries, is larger than its capital. Our results show that when we consider that there are various types of assets the ranking of systemically important countries changes. We make all our methods available by introducing a python library. Finally, we propose a more realistic model of financial contagion that merges multilayer network theory and the contingent claims sectoral balance sheet literature. The aim of this framework is to model the banking, private, and sovereign sector of each country and thus study financial contagion within the country and between countries.