The CLE_4 Conformal Loop Ensemble in a 2D simply connected domain is a random countable collection of fractal Jordan curves that satisfies a statistical conformal invariance and appears, or is conjectured to appear, as a scaling limit of interfaces in various statistical physics models in 2D, for instance in the double dimer model. The CLE_4 is also related to the 2D Gaussian free field. Given a simply connected domain D and a point z in D, we consider the CLE_4 loop that surrounds z and study the extremal distance between the loop and the boundary of the domain, and the conformal radius of the interior surrounded by the loop seen from z. Because of the confomal invariance, the joint law of this two quantities does not depend (up to a scale factor) on the choice of the domain D and the point z in D. The law of the conformal radius alone has been known since the works of Schramm, Sheffield and Wilson. We complement their result by deriving the joint law of (extremal distance, conformal radius). Both quantities can be read on the same 1D Brownian path, by tacking a last passage time and a first hitting time. This joint law, together with some distortion bounds, provides some exponents related to the CLE_4. This is a joint work with Juhan Aru and Avelio Sepulveda.