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We propose new G2-holonomy manifolds, which geometrize the Gaiotto-Kim 4d N = 1 duality
domain walls of 5d N = 1 theories. These domain walls interpolate between different extended
Coulomb branch phases of a given 5d superconformal field theory. Our starting point is the
geometric realization of such a 5d superconformal field theory and its extended Coulomb
branch in terms of M-theory on a non-compact singular Calabi-Yau three-fold and its Kahler
cone. We construct the 7-manifold that realizes the domain wall in M-theory by fibering the
Calabi-Yau three-fold over a real line, whilst varying its Kahler parameters as prescribed by
the domain wall construction. In particular this requires the Calabi-Yau fiber to pass through
a canonical singularity at the locus of the domain wall. Due to the 4d N = 1 supersymmetry
that is preserved on the domain wall, we expect the resulting 7-manifold to have holonomy G2.
Indeed, for simple domain wall theories, this construction results in 7-manifolds, which are
known to admit torsion-free G2-holonomy metrics. We develop several generalizations to new
7-manifolds, which realize domain walls in 5d SQCD theories.